;deptqgpsp ;avance-version (05/12/06) ;DEPTQ ;dept polarization transfer ;with decoupling during acquisition ;using shaped pulse for 180degree pulse on f1 - channel ; ;R. Burger & P. Bigler, J. Magn. Reson. 135, 529-534 (1998) ; ;$CLASS=HighRes ;$DIM=1D ;$TYPE= ;$SUBTYPE= ;$COMMENT= ;$OWNER=Bruker #include #include #include "p4=p3*2" "d2=1s/(cnst2*2)" "d12=20u" "p0=p3*cnst12" "DELTA=p1*4/3.1416-4u" "DELTA1=d2+p1+p4-p16-d16" "DELTA2=d2+p1-p16-d16" "DELTA3=d2-p16-d16" 1 ze 2 30m do:f2 d1 d12 pl1:f1 pl2:f2 50u UNBLKGRAD (p1 ph2):f1 p16:gp1 d16 DELTA1 (ralign (p12:sp2 ph3):f1 (p3 ph1):f2 ) DELTA2 p16:gp2 d16 (p4 ph3):f2 (p1 ph1):f1 p16:gp3 d16 DELTA3 pl0:f1 (p12:sp2 ph5):f1 (p0 ph4):f2 DELTA3 p16:gp3 d16 DELTA pl12:f2 4u BLKGRAD go=2 ph31 cpd2:f2 30m do:f2 mc #0 to 2 F0(zd) exit ph1=0 ph2=3 ph3=0 2 1 3 ph4=1 ph5=0 2 ph31=1 1 3 3 ;pl0 : 120dB ;pl1 : f1 channel - power level for pulse (default) ;pl2 : f2 channel - power level for pulse (default) ;pl12: f2 channel - power level for CPD/BB decoupling ;sp2: f1 channel - shaped pulse (180degree) ;spnam2: Crp60comp.4 ;p0 : f2 channel : p3 * cnst12 ;p1 : f1 channel - 90 degree high power pulse ;p3 : f2 channel - 90 degree high power pulse ;p4 : f2 channel - 180 degree high power pulse ;p12: f1 channel - 180 degree shaped pulse ; = 2msec for Crp60comp.4 ;p16: homospoil/gradient pulse ;d1 : relaxation delay; 1-5 * T1 ;d2 : 1/(2J(XH)) ;d12: delay for power switching [20 usec] ;d16: delay for homospoil/gradient recovery ;cnst2: = J(XH) ;cnst12: for multiplicity selection ; 0.5 ( 45 degree pulse) - all positive ; 1.0 ( 90 degree pulse) - XH only ; 1.5 (135 degree pulse) - XH, XH3 positive, XH2 negative ;NS: 4 * n, total number of scans: NS * TD0 ;DS: 8 ;cpd2: decoupling according to sequence defined by cpdprg2 ;pcpd2: f2 channel - 90 degree pulse for decoupling sequence ;use gradient ratio: gp 1 : gp 2 : gp 3 ; 31 : 31 : 31 for all C ; 0 : 31 : 31 for CHn only ; 31 : 31 : 11 for Cquat only ;for z-only gradients: ;gpz1: 31%(all/Cq) or 0%(CHn) ;gpz2: 31% ;gpz3: 31%(all/CHn) or 11%(Cq) ;use gradient files: ;gpnam1: SINE.100 ;gpnam2: SINE.100 ;gpnam3: SINE.100 ;DELTA: delay to compensate for chemical shift evolution during ; RF pulse in order to give same phase correction as ; for reference 1D spectrum ;$Id: deptqgpsp,v 1.1 2005/12/06 15:34:14 ber Exp $